谢景力团队

来源 :       作者 :       时间 : 2021-06-15     点击数:1264    打印

 

团队名称流动化学研究团队

联系方式 jlxie@mail.zjxu.edu.cn;

课题组网页: http://xielab.zjxu.edu.cn

团队介绍

科研团队现有成员6人,其中留学归国人员2人,具有博士学位的教师4人,负责人为学科带头人谢景力博士。

科研项目:

1 “连续流动光化学合成含螺吡喃类等光敏分子的多酸材料及表面组装行为研究(国家自然科学基金,No. 21771088, 2018-2021, 64万,负责人:谢景力)

2流动化学制备含鋨、銠等贵金属多重键的多酸体系及催化性能研究(国家自然科学基金,No. 21371078, 2014-201775万,负责人:谢景力) 

3)单功能荧光铂类配合物的设计合成及细胞作用机制研究(国家自然科学基金青年基金, No. 214010772015-201723万,负责人:张俊勇) 

主要研究领域

当前的研究方向有:连续流动化学在合成多酸复杂体系的应用;铂类药物的生物活性研究; 手性配位聚合物的设计,制备及其在不对称催化的应用。

流动化学方法制备新型功能材料: 流动化学是将起始原料以特定流速用加样泵打入微型反应器中,在物料流动过程中完成反应,又称微流化学,流动合成,柱流化学等。该方法在有机合成、药物开发、分析科学及石油化工等领域快速发展并已经显示出其特有的优势:a) 更加精确控制实验变量, 提高可重复性;b) 更加容易进行目标产物和副产物的分离,能将传统独立分开的多步反应一步整合起来, 更加自动化和智能化;c) 反应物料可快速进行热能转换,加快反应速度等。该方法对于绿色化学和实验室自动化具有相当重要的意义。

社会服务领域:

催化材料, 药物中间体等的研发

代表性成果(论文、专利与获奖)

1.  Haiyang Guo, Chunhua Gong, Xianghua Zeng, Hao Xu, Qingdao Zeng*, Junyong Zhang, Jingli Xie"Isopolymolybdate-based inorganic-organic hybrid compounds constructed by multidentate N-donor ligands: syntheses, structures and properties"  Dalton Trans., 2019, in press (DOI: 10.1039/C9DT00119K) (封底论文).

2.  Chunhua Gong, Haiyang Guo, Xianghua Zeng, Hao Xu, Qingdao Zeng*, Junyong Zhang, Jingli Xie "Flexible and rigid dicarboxylic acids enable the assembly of achiral and chiral 3D Co(II) metal-organic frameworks"    Dalton Trans., 2018, 47, 6917-6923 (封底论文).

3. Chunhua Gong, Junyong Zhang, Xianghua Zeng, Jingli Xie"Highly effective synthesis of Cobalt(II) metal-organic coordination polymer by  using continuous flow chemistry" Dalton Trans., 2017, 46, 25-28 (内封底论文).

4. Junyong Zhang, Chunhua Gong, Xianghua Zeng, Jingli Xie* "Continuous Flow Chemistry: New Strategies for Preparative Inorganic Chemistry" Coord. Chem. Rev., 2016, 324, 39-53.

5. Junyong Zhang, Shaoqing Chang, Bryan H.R. Suryanto, Chunhua Gong, Xianghua  Zeng, ChuanZhao,* Qingdao Zeng*, Jingli Xie"EfficientSynthesis of Ir-Polyoxometalate Cluster Using a Continuous Flow Apparatus andSTM Investigation of Its Coassembly Behaviour on HOPG Surface" Inorg. Chem., 2016, 55, 5585-5591.

6. Xianghua Zeng, Shaoqing Chang, Ke Deng*, Junyong Zhang, Hongbin Sun,  Qingdao Zeng*, Jingli Xie* “Synthesisand Molecular Structures of BINOL Complexes: An STM Investigation of 2D Self-Assembly” Cryst. Growth Des., 2015, 15 (7), 3096–3100

7.Xianghua Zeng*, Chunhua Gong, Haiyang Guo, Hao Xu, Junyong Zhang, Jingli Xie*,"Efficient heterogeneous hydroboration of alkynes: enhancing the catalytic activity by  Cu(0) incorporated CuFe2O4 nanoparticles",New J. Chem., 2018, 42, 17346-17350.

8. Junyong Zhang, Chunhua Gong, Xianghua Zeng, Jiahui Shu, Pingxiu Xiao,"Fabrication of crystalline porphyrinic polyoxometalate cluster with high thermal,stability and exploration of its photocatalytic activity" ,Polyhedron, 2017,121,95-100.

9. Chunhua Gong, Xianghua Zeng, Li Xin, Junyong Zhang*, Jingli Xie,"Construction of 3D metal-organic frameworks bearing heteropolyoxometalate units and multi-azole molecules and exploration of their photocatalytic activities" ,RSC Adv., 2017, 7, 36860-36866.

      10. Yangyang Hu, Xianghua Zeng*, Chunhua Gong, Li Xin, Jiaqi Zhang, Junyong Zhang,   Jingli Xie*, "Synthesis, structure and photocatalytic property of [Mo6O19]2- Polyoxometalate with phosphonium cation",Huaxue Tongbao, 2017, 80, 651-655. 

      11. Yanfang Geng, Ping Li, Jindong Xue, Dapeng Luo, Junyong Zhang, Lijin Shu*, Ke Deng*, Jingli Xie*, Qingdao Zeng*,"Specific distribution of orientated C70-fullerene triggered by solvent-tuned macrocycle adlayer", Nano Research., 2017, 10, 991-1000. 

     12.Hongyu Shi, Yuhong Liu, Jian Song, Xinchun Lu,* Yanfang Geng,* Junyong Zhang, Jingli Xie*, Qingdao Zeng*,"On-surface synthesis of self-assembled monolayers of Benzothiazole derivatives studied by STM and XPS", Langmuir, 2017, 33, 4216-4223.

 



 



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